Pacuła, Aleksandra http://orcid.org/0000-0003-1397-3242
Gurgul, Jacek
Micek-Ilnicka, Anna
Pietrzyk, Piotr
Ruggiero-Mikołajczyk, Małgorzata
Napruszewska, Bogna D.
Duraczyńska, Dorota
Cempura, Grzegorz
Funding for this research was provided by:
Narodowe Centrum Badań i Rozwoju (EIG CONCERT-JAPAN/1/2019)
Article History
Received: 16 September 2023
Accepted: 4 January 2024
First Online: 3 February 2024
Declarations
:
: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
: Not applicable.
: Details of the measurements (XRD, EA, N<sub>2</sub> sorption, Raman, FT-IR, XPS, SEM, EDS, TEM) are provided. Additional graphs and micrographs include: XRD patterns of the HTs, the composites, the carbon materials, H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>·19H<sub>2</sub>O (HPW) and HPW deposited on the carbon materials; the stick patterns for references: MgO (PDF 00-045-0946), Cu (PDF 04-009-2090), graphite (PDF 040-014-0362), H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>·6H<sub>2</sub>O (PDF 00-050-0304) and H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>·14H<sub>2</sub>O (PDF 00-050-0656); SEM, BF-STEM and HAADT-STEM images of the carbon materials; the Raman spectra of the carbon materials and their fittings with D1, D2, D3, D4 and G components; nitrogen sorption isotherms of the carbon materials; CV curves recorded for the carbon materials deposited on glassy carbon electrode; BSE micrographs of HPW deposited on the carbon materials; FT-IR and XPS spectra of unsupported HPW and HPW deposited on the carbon materials; the comparison of PSD, pore volume and specific surface area for the carbon materials and the catalysts; and selectivity profiles for pure HPW and HPW deposited on various carbon materials in catalytic conversion of <i>n</i>-butanol. The data on physicochemical features of additional carbon materials: C-MgMnAl-600 and C-MgMnAl-700, determined by elemental analysis, Raman spectroscopy, nitrogen sorption are also provided. The parameters of W 4f<sub>7/2</sub> line determined by XPS for HPW and the catalysts containing HPW deposited on various carbon materials are listed.
: Not applicable.